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Effect of natural gas composition on reverberatory furnace thermal efficiency for nickel alloys

https://doi.org/10.21285/1814-3520-2020-5-1159-1167

Abstract

The purpose of the article is to develop and substantiate the principles of an energy model of an industrial reverberatory furnace taking into account chemical composition and properties of natural gas as well as to calculate the furnace thermal efficiency in order to estimate its industrial performance. To conduct the research mathematical calculations are performed based on the data of chemical and physical analysis of flue gases and chimney temperature using standard graphs of excess air and enthalpy values of flue gas components. The measurement of the amount of waste pollutants is carried out using MRU Delta 65-3 gas analyzers, which identify the total amount of gases (O2, CO, NO, H2S) They determine the temperature, pressure (vacuum), calculate the content of CO2 and installation efficiency as well. Aspen Hysys program is used to verify the mathematical model. The data on the properties of natural gas are obtained i ncluding the data on chemical composition, molecular weight, calorific value, excess air during combustion. The data on flue gases are also obtained, which include the data on the burnt gas components, molecular weights, enthalpy, calorific value, flue gases ratio at the temperatures from 94°C to 316°C. The chemical reactions of combustion given with the number of moles required and formed for each reaction are used to calculate the thermal efficiency of a reverberatory furnace for nickel alloys. The calculated data are confirmed by Aspen Hysys software. Based on the studies conducted, it is found that the variable having the greatest influence on the thermal efficiency is the low calorific value, since it depends on the composition of the natural gas. The proposed methods for calculating the thermal efficiency using a computer program are effective if an operator wants to evaluate the furnace operation efficiency on site.

About the Author

V. E. Quiroz Cabascango
St. Petersburg Mining University
Russian Federation

Valeria Esthefanía Quiroz Cabascango, Postgraduate Student

2, 21st Line, St. Petersburg 199106



References

1. Stanković S, Stopić S, Sokić M, Marković B, Friedrich B. Review of the past, present, and future of the hydrometallurgical production of nickel and cobalt from lateritic ores. Metallurgical and Materials Engineering. 2020;26(2):199–208. https://doi.org/10.30544/513

2. Elliott R, Pickles CA, Forster J. Thermodynamics of the reduction roasting of nickeliferous laterite ores. Journal of Minerals and Materials Characterization and Engineering. 2016;4(6):320–346. https://doi.org/10.4236/jmmce.2016.46028

3. Barati M, Esfahani S, Utigard TA. Energy recovery from high temperature slags. Energy. 2011;36(9):5440–5449. https://doi.org/10.1016/j.energy.2011.07.007

4. Druzhinin KE, Nemchinova NV, Vasyunina NV. Improving main and auxiliary equipment for pyrometallurgical processes and testing it in production conditions. Vestnik Irkutskogo gosudarstvennogo tehnicheskogo universiteta = Proceedings of Irkutsk State Technical University. 2016;5:144–152. (In Russ.) https://doi.org/10.21285/1814-3520-2016-5-144-152

5. Bogusz A, Masset PJ. High temperature diffusion processes at the metal/slag interface. Defect and Diffusion Forum. 2012;323-325:115–120. https://doi.org/10.4028/www.scientific.net/DDF.323-325.115

6. Bunjaku A, Kekkonen M, Pietila K, Taskinen P. Effect of mineralogy and reducing agent on reduction of saprolitic nickel ores. Mineral Processing and Extractive Metallurgy. 2013;121(3):156–165. https://doi.org/10.1179/1743285512Y.0000000010

7. Bains P, Psarras P, Wilcox J. CO2 capture from the industry sector. Progress in Energy and Combustion Science. 2017;63:146–172. https://doi.org/10.1016/J.PECS.2017.07.001

8. Cruz RA, Romero SA, Vargas RM, Hallen LM. Thermodynamic analysis of the SiO2–NiO–FeO system. Journal of Non-Crystalline Solids. 2005;351(16-17):1359– 1365. http://doi.org/10.1016/j.jnoncrysol.2005.03.008

9. Fernández-Tarrazo E, Sánchez-Sanz M, Sánchez AL, Williams FA. A multipurpose reduced chemical-kinetic mechanism for methanol combustion. Combustion Theory and Modelling. 2016;20(4):613–631. https://doi.org/10.1080/13647830.2016.1162330

10. Gondaliya V, Pujara M, Mehta N. Transient heat transfer analysis of induction furnace by using finite element analysis. Indian Journal of Applied Research. 2013;3(8):231–234.

11. Reynolds WC. The element potencial method for chemical equilibrium analysis: implementation in the interaсtive program STANJAN, version 3. Department of Mechanical Engineering, Stanford University. 1986. Аvailable from: https://web.stanford.edu/~cantwell/AA283_Course_Material/STANJAN_write-up_by_Bill_Reynolds.pdf [Accessed 28th September 2019].

12. Fetisov VG, Nikolaev AK, Lykov YV. Aggregative simulation method for implementing mathematical models for gas transmission systems. Materials Science and Engineering: IOP Conference Series. 2018;327(2):022033. https://doi.org/10.1088/1757-899X/327/2/022033

13. Park Hyun Sik, Ha Min Chul, Kim Min Seok, Heo Jung Ho, Park Joo Hyun. Novel design of ferronickel smelting slag by utilizing red mud as a fluxing agent: Thermochemical computations and experimental confirmation. Calphad. 2017;56:185–195. https://doi.org/10.1016/j.calphad.2017.01.006

14. Bernhardt W. Combustion technology for the improvement of engine efficiency and emission characteristics. Symposium (International) on Combustion. 1977;16(1):223–232. https://doi.org/10.1016/S0082-0784(77)80327-5

15. Diaz CM, Landolt CA, Vahed A, Warner AEM, Taylor JC. A review of nickel pyrometallurgical operations. The Journal of the Minerals, Metals & Materials Society. 1988;40(9):28–33. https://doi.org/10.1007/BF03258548

16. Kim Sun-joong, Suzuki J, Gao X, Ueda S, Kitamura S. A kinetic model to simulate the reaction between slag and matte for the production of ferromanganese alloy from steelmaking slag. Journal of Sustainable Metallurgy. 2016;2:141–151. https://doi.org/10.1007/s40831-016-0042-z

17. Arkhazloo NB, Bouissa Y, Bazdidi-Tehrani F, Jadidi M, Morin JB, Jahazi M. Experimental and unsteady CFD analyses of the heating process of large size forgings in a gas-fired furnace. Case Studies in Thermal Engineering. 2019;14:100428. https://doi.org/10.1016/j.csite.2019.100428

18. Veshkini A, Dworkin SB. A computational study of soot formation and flame structure of coflow laminar methane/air diffusion flames under microgravity and normal gravity. Combustion Theory and Modelling. 2017;21(5):864–878. https://doi.org/10.1080/13647830.2017.1308558

19. Zhu Dе-Ging, Tian Hong-Yu, Pan Jian, Liao Hui, Guo Zheng-Qi, Xue Yu-Xiao. Comprehensive utilization status and progress of low-grade laterite nickel ore. Journal of Iron and Steel Research. 2020;5:351–362. https://doi.org/10.13228/j.boyuan.issn1001-0963.20200019

20. Taimoor AA. Virtualization of the process control laboratory using ASPEN HYSYS. Computer Applications in Engineering Education. 2016;24(6):887–898. http://doi.org/10.1002/cae.21758

21. Pickles CA, Harris CT, Peacey J, Forster J. Thermodynamic analysis of the Fe–Ni–Co–Mg–Si–O–H–S–C–Cl system for selective sulphidation of a nickeliferous limonitic laterite ore. Minerals Engineering. 2013;54:52–62. http://doi.org/10.1016/j.mineng.2013.03.029

22. Pillai R, Galiullin T, Chyrkin A, Quadakkers WJ. Methods to increase computational efficiency of CALPHADbased thermodynamic and kinetic models employed in describing high temperature material degradation. Calphad. 2016;53:62–71. http://doi.org/10.1016/j.calphad.2016.03.004


Review

For citations:


Quiroz Cabascango V.E. Effect of natural gas composition on reverberatory furnace thermal efficiency for nickel alloys. Proceedings of Irkutsk State Technical University. 2020;24(5):1159-1167. (In Russ.) https://doi.org/10.21285/1814-3520-2020-5-1159-1167

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